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Synthesis, characterization and thermal properties of boron and silicon containing preceramic oligomers

✍ Scribed by G. Ambadas; S. Packirisamy; K. N. Ninan

Book ID
110343815
Publisher
Springer
Year
2002
Tongue
English
Weight
64 KB
Volume
21
Category
Article
ISSN
0261-8028

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Phosphorus-, silicon-and chlorine-containing oligomers were synthesized by the dealkylation of methyl esters of phosphonic and phosphoric acids with dimethyldichlorsilane or diphenyldichlorsilane. It was established that the ,,-carbon atom of the methoxy group acts as an electrophilic centre. The st