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Synthesis, characterization and reactivity studies of dichloroacetylacetonato acetylacetone ruthenium(III)

โœ Scribed by Bipul C. Paul; Raj K. Poddar

Publisher
Springer
Year
1993
Tongue
English
Weight
408 KB
Volume
18
Category
Article
ISSN
0340-4285

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โœฆ Synopsis

The Ru m complex [RuClz(acac)(acacH)] (acacH = acetylacetone) was isolated in high yield by reacting RuC13 with acacH. The compound was used as a convenient starting material for the synthesis of a variety Qf Ru m complexes, viz. [RuCl2(acac)Lz] (L=PPh 3, AsPh 3, py, MeCN, Me2SO, o-phenylenediamine; L 2--phen or bipy) and M2[RuC14(acac)] (M = Me4N, Rb or Cs). The compounds were characterized by physicochemical and spectroscopic methods.

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