Immobilization, Characterization, and Preliminary Reactivity Studies of Halfsandwich Ruthenium Complexes on Silica.
✍ Scribed by Christina M. Standfest-Hauser; Thomas Lummerstorfer; Roland Schmid; Karl Kirchner; Helmut Hoffmann; Michael Puchberger
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 90 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
Dispersed atomic nickel(0) is formed during the reaction of the nickel-s-organyl complexes with silanol groups at temperatures below 373 K. That nickel is oxidized to Ni(I) by protons of the silanol groups in a consecutive step. The Ni(I) portion amounts to about 70% w/w of the Ni used. Six differen
## Abstract A novel ligand 3‐(1__H__‐imidazo[4,5‐__f__][1,10]phenanthrolin‐2‐yl)‐4__H__‐1‐benzopyran‐4‐one (ipbp) and its ruthenium(II) complexes [Ru(bpy)~2~(ipbp)]^2+^ (**1**) and [Ru(ipbp)(phen)~2~]^2+^ (**2**) (bpy=2,2′‐bipyridine, phen=1,10‐phenanthroline) were synthesized and characterized by