Synthesis, Characterization and Reactivity of New (μ-Aminocarbyne)diruthenium Complexes Containing Alkynylimino Ligands
✍ Scribed by Luigi Busetto; Fabio Marchetti; Stefano Zacchini; Valerio Zanotti
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 234 KB
- Volume
- 2004
- Category
- Article
- ISSN
- 1434-1948
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## 495 [El][BF 4 ] or [El][OSO 2 CF 3 ] (El = H, Me). The dppa backbone of 4 is readily deprotonated by KOSiMe 3 to yield the very stable zwitterionic aminocarbyne complex [(OC) 3 Fe{µ-CN(Me)2,6-xylyl}(µ-Ph 2 PNPPh 2 )Pt(PPh 3 )] 5.
The chemical behavior of triazole, thiadiazole, and triazoline derivatives of thiocarbonohydrazide towards cis-[RuCl 2 (DMSO) 4 ] (2) was studied. Reaction of 4-amino-5methylthio-3-(2-pyridyl)-1,2,4-triazole (L1) with 2 gave two diastereomeric complexes, trans,cis-[RuCl 2 (DMSO) 2 (L1)] (3) and chir
New neutral organometallic palladium(II) complexes, obtained upon treating complexes of the type [PdRX(P ʝ N)] with PPh 3 and AgCF 3 SO 3 and consist predominantly of the [PdPhI(PNMe 2 )] (1), [PdPhI(PC=NMe)] (2), [PdPhI(PC=NEt)] (3), and [PdMeCl(PNMe 2 )] (4), {PNMe 2 means N,N-dimethyl-trans-P,P i