Synthesis, characterization and reactivity of heteroleptic rare earth metal bis(phenolate) complexes
β Scribed by Qi, Ruipeng; Liu, Bao; Xu, Xiaoping; Yang, Zijian; Yao, Yingming; Zhang, Yong; Shen, Qi
- Book ID
- 111890096
- Publisher
- Royal Society of Chemistry
- Year
- 2008
- Tongue
- English
- Weight
- 348 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1477-9226
- DOI
- 10.1039/b804914a
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The reaction of rare earth silylamides Ln[N(SiHMe 2 ) 2 ] 3 (thf) n performed on the solvent-free, dinuclear yttrium derivative 5 revealed an unusual Β΅ 2 ,Ξ· 4 :Ξ· 1 -coordination of the [n = 1 for Sc (1a); n = 2 for Y (1b), La (1c), Nd (1d)] with trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamido)cyc
A series of eleven heteroleptic bis(phthalocyaninato) rare earth double-deckers [M III (pc){pc(a-OC 5 H 11 ) 4 }] 1 Β± 11 (M Y, SmΓLu; pc phthalocyaninato; pc(a-OC 5 H 11 ) 4 1,8,15,22-tetrakis(1-ethylpropoxy)phthalocyaninato) were prepared as racemic mixtures by [M III (pc)(acac)]-induced (acac acet