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Synthesis, characterization, and crystal structures of two 6-cobalt-containing dimeric polyoxoanions: [Co2(H2O)10Co4(H2O)2(B-α-XW9O34)2]8− (X = Ge and Si)

✍ Scribed by Zhiming Zhang; Enbo Wang; Yangguang Li; Haiyan An; Yanfei Qi; Lin Xu


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
619 KB
Volume
872
Category
Article
ISSN
0022-2860

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Second sphere coordination in anion binding: Synthesis, characterization of [Co(phen) 2 CO 3 ]XÁnH 2 O where X = o-nitrophenolate(onp), p-nitrophenolate(pnp), 2,4-dinitrophenolate(dnp), 2,4,6-trinitrophenolate(tnp) and single crystal X-ray structures of [Co(phen) 2 CO 3 ](onp)Á2H 2 O and [Co(phen) 2