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Second sphere coordination in anion binding: Synthesis, characterization of [Co(phen)2CO3]X·nH2O where X = o-nitrophenolate(onp), p-nitrophenolate(pnp), 2,4-dinitrophenolate(dnp), 2,4,6-trinitrophenolate(tnp) and single crystal X-ray structures of [Co(phen)2CO3](onp)·2H2O and [Co(phen)2CO3](dnp)·4.5H2O

✍ Scribed by Ajnesh Singh; Raj Pal Sharma; Paula Brandão; Vitor Félix; Paloth Venugopalan


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
891 KB
Volume
892
Category
Article
ISSN
0022-2860

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✦ Synopsis


Second sphere coordination in anion binding: Synthesis, characterization of [Co(phen) 2 CO 3 ]XÁnH 2 O where X = o-nitrophenolate(onp), p-nitrophenolate(pnp), 2,4-dinitrophenolate(dnp), 2,4,6-trinitrophenolate(tnp) and single crystal X-ray structures of Co(phen) 2 CO 3 Á2H 2 O and Co(phen) 2 CO 3 Á4.


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To explore the role of weak interactions in aryldicarboxylate binding, the hydrated complex salt, [Co(phen 4 ¼ terephthalateÞ was synthesized and characterized by elemental analyses, spectroscopic studies (IR, UV/Visible, 1 H, 13 C and 59 Co NMR), physical measurements and single-crystal diffractio