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Synthesis, characterization and crystal structure of a novel coordination compound based on the mixed N- and O- donor ligands exhibiting the metal ion-bridged ligand–ligand interaction: [Zn(2,2′-bipy)(Phmal)(H2O)]·2H2O

✍ Scribed by Kou-Lin Zhang; Hai-Wei Kuai; Guo-Wang Diao


Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
194 KB
Volume
779
Category
Article
ISSN
0022-2860

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A heterometallic Zn,Nb compound of the formula [{Zn(bpy) 2 } 2 (l-C 2 O 4 )][Zn(bpy) 2 (l-C 2 O 4 )NbO(C 2 O 4 ) 2 ] 2 Á0.5bpyÁ7H 2 O (1) (bpy = 2,2 0 -bipyridine) has been synthesized by the reaction of the tris(oxalato)oxoniobate(V) anion, [NbO(C 2 O 4 ) 3 ] 3À and [Zn(bpy) 3 ] 2+ in an aqueous so