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Synthesis, characterization, and conductivity of (μ-cyano)(phthalocyaninato)cobalt(III)

✍ Scribed by Metz, Josef; Hanack, Michael


Book ID
120189877
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
361 KB
Volume
105
Category
Article
ISSN
0002-7863

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Synthesis and characterization of μ-cyan
✍ Naglaa Fahmy; Michael Hanack 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 392 KB

## Abstract (Octaethylporphyrinato)cobalt(II), OEPCo (1), reacts with sodium cyanide and undergoes simultaneous oxidation with air oxygen to form sodium dicyano(octaethylporphyrinato)‐cobalt(III), Na[OEPCo(CN)~2~] (2), which is converted into μ‐cyano(octaethylporphyrinato)‐cobalt(III), [OEPCoCN]~__