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Synthesis, characterization, and computational study of some new organotellurium compounds containing azomethine groups

✍ Scribed by Ali Z. Al-Rubaie; Wasfi A. Al-Masoudi; Shaker A. N. Al-Jadaan; Abraham F. Jalbout; Ali Jameel Hameed

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
326 KB
Volume
19
Category
Article
ISSN
1042-7163

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✦ Synopsis

The reaction of ortho-mercurated anilines with benzaldehyde gave the ortho-mercurated Schiff bases. The reaction of the mercurated Schiff bases with tellurium tetrabromide in 1:1 and 2:1 mole ratio using dry chloroform as solvent gave the ortho-tellurated Schiff bases compounds ArTeBr 3 and Ar 2 TeBr 2 , respectively, in good yields (where

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## Abstract A new series of organotellurium(IV) compounds based on di(cyclohexylmethyl)telluride (1) (i.e., (C~6~H~11~CH~2~)~2~TeX~2~ and (C~6~H~11~CH~2~)~2~Te(R)X) was prepared by the reaction of compound 1 with halogens, N‐bromosuccinimide, and alkyl halides. Phenylation of (C~6~H~11~CH~2~)~2~TeX

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