Synthesis, characterization and catalytic activity of Rh (PPh3)2 (en)Cl complex
β Scribed by D T Gokak; B V Kamath; R N Ram
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 379 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0268-2605
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## Abstract Treatment of [OsCl~2~(PPh~3~)~3~] with HCβ‘CR (R = Ph, __p__βtolyl, CMe~3~) in the presence of HCl gives the corresponding trichloro(carbyne) complexes [OsCl~3~(β‘CCH~2~R)(PPh~3~)~2~] in good yields. The vinylidene complexes [OsCl~2~(=C=CHR)(PPh~3~)~2~] (R = Ph, __p__βtolyl, CMe~3~) are,
Synthesis, spectroscopy, and crystal structures of [Cu(ca 2 en) 2 ]ClO 4 (1) and [Cu(ca 2 en)(PPh 3 ) 2 ]ClO 4 (2) (ca 2 en N,N'-bis(trans-cinnamaldehyde)ethylenediimine) are reported. Compound 1 crystallizes in the orthorhombic space group Pbca, with a 12.5647( ), b 21.8203(11), c 27.992(2) Γ€, V 76