Synthesis, Characterization and Catalytic Activity of New N-Heterocyclic Bis(carbene)ruthenium Complexes
✍ Scribed by İsmail Özdemir; Serpil Demir; Nevin Gürbüz; Bekir Çetinkaya; Loïc Toupet; Christian Bruneau; Pierre H. Dixneuf
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 465 KB
- Volume
- 2009
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Four ruthenium-N-heterocyclic carbene complexes (3-6) have been prepared and the new compounds characterized by C, H, N analyses, 1 H-NMR and 13 C-NMR. The reduction of ketones to alcohols via transfer hydrogenation was achieved with catalytic amounts of complexes 3-6 in the presence of t-BuOK.
## Abstract The synthesis of new __N__,__N__‐bidentate ligands based on a π‐deficient N‐heterocyclic benzhydrylamine core is described. The corresponding air‐stable palladium complexes are obtained in high yields and fully characterized by NMR spectroscopy and X‐ray structure determination. These n