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Synthesis, characterization and catalytic activity in the hydroformylation of 1-hexene and styrene of water-soluble rhodium complex [Rh(μ-Pz)(CO)(TPPMS)]2 (Part 1)

✍ Scribed by P.J. Baricelli; R. Santos; E. Lujano; A.J. Pardey


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
489 KB
Volume
207
Category
Article
ISSN
1381-1169

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A novel water soluble phosphine, N,N-dipolyoxyethylene-substituted-2-(diphenylphosphino)phenylamine (PEO-DPPPA), was synthesized by a two-step ethoxylation of 2-(diphenylphosphino)phenylamine (2-Ph 2 P-C 6 H 4 NH 2 , DPPPA). In the first step, DPPPA was ethoxylated without catalyst to give an interm