Influence of the addition of thiophenes on the catalytic activity of the rhodium binuclear complex [Rh(CO)(μ-Pz)(TPPTS)]2 during the biphasic hydroformylation of 1-hexene
✍ Scribed by Pablo J. Baricelli; Francisco López-Linares; Sheyla Rivera; Luis G. Melean; Victor Guanipa; Patrik Rodriguez; Mariandry Rodriguez; Merlin Rosales
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 526 KB
- Volume
- 291
- Category
- Article
- ISSN
- 1381-1169
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The hydrosoluble complex [Rh(-Pz)(CO)(TPPMS)] 2 , Pz = pyrazolate ligand, and TPPMS = (C 6 H 5 ) 2 P(C 6 H 4 SO 3 Na) was used as catalytic precursor in the two phase hydrogenation reaction of the individual olefins (1-hexene, styrene, cyclohexene and 2,3-dimethyl-1-butene) to give the main expected
A novel water soluble phosphine, N,N-dipolyoxyethylene-substituted-2-(diphenylphosphino)phenylamine (PEO-DPPPA), was synthesized by a two-step ethoxylation of 2-(diphenylphosphino)phenylamine (2-Ph 2 P-C 6 H 4 NH 2 , DPPPA). In the first step, DPPPA was ethoxylated without catalyst to give an interm