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Synthesis, characterization and antibacterial properties of symmetric 1,1′-ferrocene derived Schiff-base ligands and their Co(II), Cu(II), Ni(II) and Zn(II) chelates

✍ Scribed by Zahid H. Chohan; M. Praveen

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
63 KB
Volume
14
Category
Article
ISSN
0268-2605

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✦ Synopsis

Symmetric 1,1'-dimethylferrocene derived Schiff-base ligands have been prepared by the condensation reaction of 1,1'-diacetylferrocene with 2-aminopyrazine, 2-aminopyridine and 2aminothiazole respectively. Their transition metal chelates, of the type [M(L)]Cl 2 [M = Cu(II)] and [M(L)(Cl 2 )] [M = Co(II), Ni(II) and Zn(II)] have been prepared. The synthesized Schiff-base ligands and their metal(II) chelates have been characterized by their physical, analytical and spectral data.

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## Abstract Polymer metal complexes of poly(styrene sulfonic acid‐__co__‐maleic acid) and Cu(II), Ni(II), Co(II), and Zn(II) were synthesized. The magnetic, spectral, and thermal properties, as well as the electrical conductivities, of the chelates were investigated, and possible structures were as