✦ LIBER ✦

Synthesis, Characterisation, Complexation and Electrochemistry of Linear Tridentate FcE(CH2)3E′(CH2)3EFc (E, E′ = Se or Te) Ligands: X-ray Crystal Structures of FcSe(CH2)3Se(CH2)3SeFc and [PtCl{FcSe(CH2)3Se(CH2)3SeFc}]PF6 {Fc = [Fe(η5-C5H5)(η5-C5H4)]}

✍ Scribed by Su Jing; Christopher P. Morley; Christopher A. Webster; Massimo Di Vaira

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 608 KB
Volume: 2008
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200800316

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✦ Synopsis

Abstract

A series of linear tridentate ligands, FcE(CH~2~)~3~E′(CH~2~)~3~EFc (E, E′ = Se or Te), was synthesised. Their chloropalladium(II) and chloroplatinum(II) complexes were also prepared. The new compounds were characterised by a range of spectroscopic and analytical techniques, including multinuclear NMR spectrometry and X‐ray crystallography. In an electrochemistry study of the complexes no communication between the ferrocenyl centres was observed, regardless of the through‐bond Fe**···**Fe distance.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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