Synthesis, characterisation and crystal structure of polymeric chloro(diethyl telluride)copper(I), (Et2Te·CuCl)∞
✍ Scribed by Raj K. Chadha; John E. Drake
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 614 KB
- Volume
- 286
- Category
- Article
- ISSN
- 0022-328X
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## Abstract The copper‐deficient title compound La~3~Cu~5‐x~Te~7~ (x = 0.07, 0.14, 0.12) is synthesized from the elements (graphite crucible in a sealed silica tube, 1073 K, 14 d) and characterized by single crystal XRD, electrical measurements, and LMTO band structure calculations.
## Abstract The reaction of copper(I) chloride with acetonethiosemicarbazone (tscac) in a copper to tscac molar ratio of 1:2 forms the cationic complex [Cu(tscac)~2~]Cl (1). When the ratio of the copper to tscac was reduced to 1:1, a dimeric complex [Cu~2~Cl~2~(tscac)~2~]~2~ (2) was obtained. In co