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Synthesis, characterisation and computational studies on a novel one-dimensional arrangement of Schiff-base Mn3 single-molecule magnet

✍ Scribed by Lin, Po-Heng; Gorelsky, Serge; Savard, Didier; Burchell, Tara J.; Wernsdorfer, Wolfgang; Clérac, Rodolphe; Murugesu, Muralee


Book ID
121217302
Publisher
Royal Society of Chemistry
Year
2010
Tongue
English
Weight
606 KB
Volume
39
Category
Article
ISSN
1477-9226

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Two new members of the (A 3 ZnMnO 6 ) α (A 3 Mn 3 O 9 ) β one-dimensional homologous series have been synthesised with the compositions Sr 4 Mn 2 ZnO 9 and Ba 5 Mn 3 ZnO 12 . Their structures can be described as a hexagonal array of infinite 1Dchain polyhedra, running parallel to the c-axis, formed