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Synthesis, Microstructural Characterization and Magnetic Study of Two New One-Dimensional Members of the (A3ZnMnO6)α (A3Mn3O9)β Homologous Series (A: Ba, Sr).

✍ Scribed by Maria Hernando; Khalid Boulahya; Marina Parras; Jose M. Gonzalez-Calbet

Publisher
John Wiley and Sons
Year
2003
Weight
70 KB
Volume
34
Category
Article
ISSN
0931-7597

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Two new members of the (A 3 ZnMnO 6 ) α (A 3 Mn 3 O 9 ) β one-dimensional homologous series have been synthesised with the compositions Sr 4 Mn 2 ZnO 9 and Ba 5 Mn 3 ZnO 12 . Their structures can be described as a hexagonal array of infinite 1Dchain polyhedra, running parallel to the c-axis, formed

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The (alpha =3, beta =2) member of the (A3ABO6) (A3B3O9) homologous series has been stabilised in the Sr-Rh-O system for a [Sr10(Sr0.5Rh1.5)TP(Rh6)Oh]O24 composition. The structural characterisation has been performed by powder X-ray and electron diffraction measurements and high-resolution electron