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Synthesis and X-ray structure of a ruthenium cluster with a chiral oxazoline ligand

✍ Scribed by Sumit Bhaduri; Niteen Sapre; Peter G Jones


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
358 KB
Volume
509
Category
Article
ISSN
0022-328X

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The reaction of Rh 2 (O 2 CR) 4 (R = CH 3 , CF 3 ) with the chiral phosphane (2S,5S)-2,5-dimethyl-1-phenylphospholane (PC\* H), results in the formation of two diastereoisomers of Rh 2 (O 2 CCR) 2 (PC\*) 2 , with (P) and (M) configuration. These can easily be isolated by chromatographic methods to o