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Synthesis and X-ray diffraction structures of novel half-sandwich Os(ii)-and Ru(ii)-hydroxamate complexes

✍ Scribed by Godó, Attila J.; Bényei, Attila Cs.; Duff, Brian; Egan, Denise A.; Buglyó, Péter


Book ID
111653418
Publisher
The Royal Society of Chemistry
Year
2012
Tongue
English
Weight
691 KB
Volume
2
Category
Article
ISSN
2046-2069

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## Abstract Compounds consisting of a substrate‐binding site and a Ni^II^ or Mn^III^ salen moiety have been synthesized. These compounds are able to epoxidise a variety of alkenes in the presence of sodium hypochlorite or iodosylbenzene. The X‐ray structure of the nickel(II) complex is reported.