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Synthesis and X-ray structure of a novel cavity-containing dinuclear nickel(II) complex

✍ Scribed by P. A. Gosling; R. P. Sijbesma; R. J. M. Nolte; A. L. Spek

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
294 KB
Volume
112
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

Compounds consisting of a substrate‐binding site and a Ni^II^ or Mn^III^ salen moiety have been synthesized. These compounds are able to epoxidise a variety of alkenes in the presence of sodium hypochlorite or iodosylbenzene. The X‐ray structure of the nickel(II) complex is reported.

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Template reactions are described in which pentanedione or salicylaldehyde are reacted with aminoethanethiol in the presence of Ni(OAc) 2 β€’4H 2 O resulting directly in the reported nickel complexes. In both reactions a tridentate chelating N,O,S ligand is formed, which in the complexes is dianionic w