A hypervalent arsorane with an As-Fe bond [6: Rf 2 As\*FeCp(CO) 2 (Rf: o-C 6 H 4 C(CF 3 ) 2 O-)] was synthesized by the reaction of the arsoranide anion (4-Et 4 N: Rf 2 As\* -Et 4 N โซืโฌ ) with CpFe(CO) 2 I (5) in the presence of AgBF 4 . Diastereomeric arsoranes {7a and 7b: Rf 2 As\*Fe\*Cp(CO)(PPh 3
Synthesis and x-ray crystal structures of hypervalent hexacoordinate antimony compounds without halogen ligands
โ Scribed by Yukiya Wakisaka; Yohsuke Yamamoto; Kin-ya Akiba
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 144 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1042-7163
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