Crystalline Hosts Based on the Assembly of Anthracene and Bulky Alcoholic Groups – Host Synthesis, Complex Formation, and X-ray Crystal Structures of Several Inclusion Compounds
✍ Scribed by Edwin Weber; Thomas Hens; Qi Li; Thomas C. W. Mak
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 383 KB
- Volume
- 1999
- Category
- Article
- ISSN
- 1434-193X
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✦ Synopsis
A series of new clathrate host molecules (1-10) containing hydrocarbons are reported (143 examples of clathrates). The inclusion properties and the clathrate stoichiometries depend two diarylhydroxymethyl groups attached to different positions (1,5 or 1,8) of a basic anthracene construction unit in a systematic manner on the structure of the host molecules. The crystal structures of six selected clathrates of have been synthesized. Their clathrate formation properties with a variety of organic guests, including amines, alcohols, different classes of compound have been determined by Xray diffraction. ketones, and other dipolar aprotic compounds or aromatic subunits, such as naphthalene or anthracene, have also pro- [a] Institut für Organische Chemie, Technische Universität cedures [17] [19] from 1,5-dichloro-and 1,8-dichloro-9,10-Bergakademie Freiberg, anthraquinone, respectively. All organolithium reactions Leipziger