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Synthesis and X-ray crystal structure of a novel cerium(IV) arylsiloxide

✍ Scribed by P.S. Gradeff; K. Yunlu; A. Gleizes; J. Galy


Book ID
108428273
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
475 KB
Volume
8
Category
Article
ISSN
0277-5387

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Reactions of trialkylalanes AlR 3 (R = Me, Et, tBu) and triorganylbismuthanes BiRЈ 3 (RЈ = iPr, SiMe 3 ) were performed and the products investigated both in solution and in the solid state. Et 3 Al-Bi(SiMe 3 ) 3 (2), tBu 3 Al-Bi(SiMe 3 ) 3 (3), and tBu 3 Al-Bi(iPr) 3 ( 6) are stable Lewis acid-base