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Synthesis, reactivity, and x-ray crystal structure of dichloro(phthalocyaninato)titanium(IV)

✍ Scribed by Goedken, V. L.; Dessy, G.; Ercolani, C.; Fares, V.


Book ID
120641653
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
677 KB
Volume
24
Category
Article
ISSN
0020-1669

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Dichloro(phthalocyaninato)niobium(IV), PcNbCl 2, has been isolated as a new polymorph and its X-ray crystal structure solved. Crystals are triclinic: formula C 32 H 16 Cl 2 N 8 Nb , space group P1, cell parameters a = 8.707(2) Γ…, b = 12.288(3) Γ…, c = 12.801(3) Γ…, Ξ± = 80.72(2) Β°, Ξ² = 85.43(2) Β°, Ξ³ =

Interligand carbon-carbon .sigma.-bond b