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Synthesis and Tunable Reactivity of N-Heterocyclic Germylene

✍ Scribed by Yun Xiong; Shenglai Yao; Matthias Driess

Book ID
112006660
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
346 KB
Volume
7
Category
Article
ISSN
1861-4728

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## Abstract The five‐membered N‐heterocyclic germylenes (NHGe) 1a–3a, with or without benzo or naphtho anellation, react with [Mo(CO)~3~(cht)] (cht = 1,3,5‐cycloheptatriene) to form the__fac__‐[(NHGe)~3~Mo(CO)~3~] complexes 1b–3b. Similarly, [Ni(bnNHGe)~4~] was obtained from the benzo‐anellated ger