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Theoretical Study of Methyl-Pd II N-Heterocyclic Silylene and Germylene Complexes: Comparisons to N-Heterocyclic Carbene Reactivity

✍ Scribed by McGuinness, David S.; Yates, Brian F.; Cavell, Kingsley J.


Book ID
127273303
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
173 KB
Volume
21
Category
Article
ISSN
0276-7333

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Study of the reactivity of 2-methyl-3-bu
✍ Alberto Acosta-RamΓ­rez; David Morales-Morales; Juan Manuel Serrano-Becerra; Alma πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 English βš– 245 KB

The catalytic isomerization of 2-methyl-3-butenenitrile (2M3BN) was performed in the presence of Ni(0) with N-heterocyclic carbene (NHC) ligands. On using bulky aromatic substituents on the NHC nitrogen atoms, the isomerization reaction proceeded at room temperature within 15 min: a total conversion