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Synthesis and transport properties of thin film composite membranes. II. Preparation of sulfonated poly(phenylene oxide) thin film composite membranes for the purification of alberta tar sands waste waters

✍ Scribed by R. Y. M. Huang; J. J. Kim


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
431 KB
Volume
29
Category
Article
ISSN
0021-8995

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✦ Synopsis


Thin film composite membranes of sulfonated poly(phenylene oxide) (SPPOk-polysulfone (PS) (SPPO-PS) were prepared by coating the hydrogen or sodium form of SPPO onto various porous substrates such as polysulfone (PS). The effects of membrane preparation conditions and feed water variables on the salt rejection and production rates were investigated using reverse osmosis. Purification of the waste waters from the Alberta heavy oil fields for desalination and recycling use was carried out. Production rates and salt rejections for the various feeds were found to be in the range of 5-20 gfd (gallons/fF day) and 80-99% respectively at 600 psig and 2OC, depending on the experimental conditions and membrane properties.


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Novel membranes based on sulfonated poly (phenylene oxide) (SPPO) was developed. SPPO membranes in the hydrogen form were converted to metal ion forms. The effect of exchange with metal ions including monovalent (Li ϩ , Na ϩ , K ϩ ), divalent (Mg 2ϩ , Ba 2ϩ , Ca 2ϩ ) and trivalent (Al 3ϩ ) ions was