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Synthesis and thermolysis of N-heteroarylacetylazides and α-oximino-α-(N-heteroaryl)acetylazides

✍ Scribed by Masatomo Iwao; Tsukasa Kuraishi


Book ID
112125673
Publisher
Journal of Heterocyclic Chemistry
Year
1979
Tongue
English
Weight
744 KB
Volume
16
Category
Article
ISSN
0022-152X

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Organometallic addition to tert-butanesufinyl ketimines derived from diaryl and aryl-heteroaryl ketones provided the corresponding a,a-diaryl and a-aryl-a-heteroaryl alkylamines in good yield with high diastereoselectivity. In many cases, imine facial selectivity is reversed on changing the organome