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Synthesis and thermal reactivity of a novel bis-salicylaldimino enediyne and its Cu(II) and Ni(II) complexes

โœ Scribed by Amit Basak; Kakali Rani Rudra

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
115 KB
Volume
41
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A novel bis-salicylaldimino enediyne 1, along with its Ni(II) and Cu(II) complexes 6 and 7, respectively, were prepared. Dierential Scanning Calorimetric studies revealed an elevation of the onset temperature for Bergman cyclization upon complexation.

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Synthesis and thermal behaviour of a novel diazaenediyne and its copper(II)-complex
โœ Amit Basak; Jagadish Shain ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 104 KB

A novel 12-membered diazaenediyne and its Cu(II)-complex have been synthesized. Differential Scanning Calorimetric (DSC) measurements revealed a depression of onset temperature for Bergman cyclization. ยฉ1998El~vierScienceLtd. AIId~ts~se~ed.