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Synthesis and Thermal Reaction of 1,3-Bis(alkylseleno)allenes

✍ Scribed by Shimizu, Toshio; Miyasaka, Daisuke; Kamigata, Nobumasa


Book ID
126278260
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
103 KB
Volume
2
Category
Article
ISSN
1523-7060

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Reactions of Ph2C3 dianion with alkyl thiocyanates or ethylene 1,2-dithioeyanate give 1,3bis(alkylthio)allenes or tetrathiacyclic bisallene, respectively. Thermal reactions of 1,3bis(benzylthio)allene and tetrathiacyclic bisallene afford 2,3,5-uiphenylthiophene and 1,2-bismethylidene cyeiobutane der