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Fluorine-containing allenes 8. Reaction of 1,1-bis (trifluoromethyl)-3,3-bis (alkoxycarbonyl) allenes with phenylacetylene

โœ Scribed by N. S. Mirzabekyants; Yu. A. Cheburkov; I. L. Knunyants


Book ID
112447847
Publisher
Springer
Year
1977
Tongue
English
Weight
367 KB
Volume
26
Category
Article
ISSN
1573-9171

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Reactions of Ph2C3 dianion with alkyl thiocyanates or ethylene 1,2-dithioeyanate give 1,3bis(alkylthio)allenes or tetrathiacyclic bisallene, respectively. Thermal reactions of 1,3bis(benzylthio)allene and tetrathiacyclic bisallene afford 2,3,5-uiphenylthiophene and 1,2-bismethylidene cyeiobutane der