Synthesis and study of iodonium borate salts as photoinitiators

✍ Scribed by Kesheng Feng; Hongmei Zang; Dustin Martin; Thomas L. Marino; D. C. Neckers

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 241 KB
• Volume: 36
• Category: Article
• ISSN: 0887-624X
• DOI: 10.1002/(sici)1099-0518(19980730)36:10<1667::aid-pola20>3.0.co;2-d

✦ Synopsis

Iodonium butyltriphenylborate salts (Ar{I / {ArrPh 3 B 0 {R), (R|Bu) were found to be more efficient than iodonium tetraphenylborate salts (R|Ph) when used as photoinitiators for the polymerization of acrylates. Relative photodecomposition rates were also different. It was found from a study of the photoreaction of iodonium borate salts with a model monomer, methyl methacrylate, that iodonium butyltriphenylborate salts simultaneously produce a butyl radical from the borate anion and an aryl radical from the iodonium cation upon irradiation. Both radicals initiate polymerization. Iodonium tetraphenylborate salts were found to release an aryl radical, but only from the iodonium cation. Iodonium borate salts exhibit strong absorption below 300 nm with a tail absorption above 400 nm. Thus, iodonium butyltriphenyl borate salts are efficient photoinitiators even when used with visible light. When a photosensitizer such as 5,7-diiodo-3-butoxy-6-fluorone is employed, iodonium butyltriphenylborate salts are rendered much more efficient for visible light photopolymerization.