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Synthesis and Study of Hexanuclear Molybdenum Clusters Containing Thiolate Ligands

✍ Scribed by Szczepura, Lisa F.; Ketcham, Karen A.; Ooro, Betty A.; Edwards, Julia A.; Templeton, Jeffrey N.; Cedeño, David L.; Jircitano, Alan J.


Book ID
111951814
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
329 KB
Volume
47
Category
Article
ISSN
0020-1669

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Chiral racemic rhenium thiolate complexes [CpRe-SCH 2 CH 2 NHAc (8), SCH 2 CH 2 C(O)OH (9). A milder synthesis using hydrated sodium carbonate as a base (NO)(PPh 3 )(SR)] were obtained under either acidic or basic conditions. Thus, when [CpRe(NO)(PPh 3 )(CH 3 )] (1) was provided 8 and compounds with