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Synthesis and Structures of Vinamidine MnII, ZnII, and CdII Iodine Derivatives

✍ Scribed by Jörg Prust; Kerstin Most; Ilka Müller; Andreas Stasch; Herbert W. Roesky; Isabel Usón

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
267 KB
Volume
2001
Category
Article
ISSN
1434-1948

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✦ Synopsis

We have focused on the synthesis of monomeric, functionalized starting materials containing manganese(II), zinc(II), and cadmium(II) by taking advantage of the sterically demanding and chelating property of the substituted vinamidine ligand 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene (NacNacH). Metal iodine derivatives containing vinamidines as the bulky ligand can be regarded as interesting precursors for preparing complexes with low-valent metal centers by reduction as [a]

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