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Synthesis and structures of three 1-aminoethylidenediphosphonate compounds with transition-metal ions

✍ Scribed by Ming Li; Jiangfeng Xiang; Simin Wu; Shuoping Chen; Liangjie Yuan; Hua Li; Hanjiang He; Jutang Sun

Book ID
103837746
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
411 KB
Volume
840
Category
Article
ISSN
0022-2860

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## Abstract We report an efficient convergent synthesis of a new type of C‐clamp ligand with a 1,2‐diethynylarene scaffold involving a chelate host capable of binding a guest molecule in its __endo__‐dicarboxylate pocket. The chemistry involves a combination of palladium‐catalyzed Sonogashira, Heck