Synthesis and Structures of Silver(I) Adducts with 4-Amino-3,5-diisobutyl-4H-1,2,4-triazole: The Identification of a New Type of Ag3tz6Cluster
✍ Scribed by Huang, Zhan-Dong; Chen, Jun-Xian; Wang, De-Liang; Yang, Guang
- Book ID
- 120226096
- Publisher
- Springer
- Year
- 2012
- Tongue
- English
- Weight
- 311 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1040-7278
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## Abstract The reaction of thiocarbohydrazide with carboxylic acids at the melting temperature allows an improved preparation of the S‐substituted 4‐amino‐3‐mercapto‐1,2,4‐triazole heterocycles. The crude 4‐amino‐5‐mercapto‐1,2,4‐triazoles react easily with carboxylic acids or carboxylic acid chlo
A series of 4-(alkylidene/arylidene)amino-5-(2-furanyl)-2.4-dihydro-3H-I .2.4-triazolc-3-1hiones (2) and 6-aryl-3-(2-furanyl)-7H-12.4-triazolo[3,4-b]( 1.3.41 thiadiazines (3) werc synthesized. The configuration of 2g was assigned on che basis of 'H-NMR data. Of the new derivatives tesced. only 2b. 2