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Synthesis and Structures of Oxyanion Encapsulated Copper(I)−dppm Complexes (dppm = Bis(diphenylphosphino)methane)

✍ Scribed by Bera, Jitendra K.; Nethaji, Munirathnam; Samuelson, Ashoka G.


Book ID
120071586
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
330 KB
Volume
38
Category
Article
ISSN
0020-1669

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Isomerically pure nitrile complexes cis-[Ru(dppm) 2 Cl(NCR)] + (2 a±d) are formed upon chloride displacement from cis-[Ru(dppm) 2 Cl 2 ] (1) or, alternatively, by ligand substitution from the acetonitrile complex 2 a. This latter approach does also allow for the introduction of pyridine (3 a,b), hep