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Anion-Controlled Nuclearity and Metal−Metal Distances in Copper(I)−dppm Complexes (dppm = Bis(diphenylphosphino)methane)

✍ Scribed by Bera, Jitendra K.; Nethaji, Munirathnam; Samuelson, Ashoka G.

Book ID
121499329
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
158 KB
Volume
38
Category
Article
ISSN
0020-1669

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Synthesis and characterization of triangulo copper(I) complexes containing mono- and bicapping systems of asymmetric .mu.3-.eta.1-acetylide ligands: molecular structures of [Cu3(.mu.3-.eta.1-C.tplbond.CPh)(.mu.-dppm)3][BF4]2, [Cu3(.mu.3-.eta.1-C.tplbond.CPh)2(.mu.-dppm)3][BF4], and [Cu3(.mu.3-.eta.1-C.tplbond.CPh)(.mu.3-Cl)(.mu.-dppm)3][BF4] [dppm = bis(diphenylphosphino)methane]
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