Synthesis and Structures of [In 4 (4,4‘-bipy) 3 (HPO 4 ) 4 (H 2 PO 4 ) 4 ]·4H 2 O and In 4 (4,4‘-bipy) 3 (HPO 4 ) 4 (H 2 PO 4 ) 4 , Indium Phosphates with a Pillared Layer Structure
✍ Scribed by Lii, Kwang-Hwa; Huang, Yuh-Feng
- Book ID
- 127293909
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 88 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0020-1669
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Ammonium zinc phosphate, (NH 4 )Zn(HPO 4 )(H 2 PO 4 ), is built up from in®nite 4-ring chains of vertex-sharing ZnO 4 and (H/ H 2 )PO 4 tetrahedra [d av (ZnÐO) = 1.943 (2) A Ê and d av (PÐO) = 1.534 (2) A Ê ] crosslinked by ammonium cations. The intrachain OÐHÁ Á ÁO hydrogen bond appears to be essen
A layered cadmium phosphate of the formula K 4 [Cd 3 (HPO 4 ) 4 (H 2 PO 4 ) 2 ], I, containing six-membered apertures, constituting the 5rst example of an open-framework cadmium phosphate, has been synthesized under hydrothermal conditions. Crystal data: monoclinic, P2 1 /n (No. 14), a ؍ 9.0698( 3