Synthesis and Structures of Bi(1,1-stannole)s
✍ Scribed by Masaichi Saito; Ryuta Haga; Michikazu Yoshioka
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 121 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-1948
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## Abstract 1,1′‐Bi(__endo__,__exo__,__syn__‐pentacyclo[3.3.3.0^2,4^.0^6,8^.0^9,11^]undecyl)[1,1′‐bi(trishomobarrelenyl)] (**4**) has been prepared as a 1:1 mixture of its __meso__‐ and __d__,__l__‐diastereomers in six steps from trishomobarrelene **1** via the amine **5**, the __N__,__N__′‐bis(tri
A series of 1,8-bis(phosphino)naphthalenes 2 was prepared by treating 1,8-dilithionaphthalene with the appropriate chloro-or bromophosphines RRЈPX; R, RЈ ס Me (for 2a), iPr (for 2c), Cy (for 2d), Ph (for 2f); R ס tBu, RЈ ס Ph (for 2e) (X ס Cl) and R, RЈ ס Et; X ס Br (for 2b). The resulti