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Synthesis and structure proof of diethyl diacetylmaleate and diethyl diacetylfumarate

✍ Scribed by Airy, Subhash C.; Martin, Craig; Sullivan, John M.

Book ID
126935822
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
306 KB
Volume
44
Category
Article
ISSN
0022-3263

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Diethyl phosphonomethyltriflate, prepared from diethyl hydroxymethylphosphonate, readily reacts in good to excellent yields with a variety of oxygen and nitrogen nucleophiles. Currently, no mild method exists for effecting displacement reactions on the a-carbon of phosphonates. Such a reaction woul