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Synthesis and Structure of Vitamin B12-Derivatives with a Modified Ribose-Unit

✍ Scribed by Renate B. Hannak; Sigrid Gschösser; Klaus Wurst; Bernhard Kräutler


Publisher
Springer Vienna
Year
2007
Tongue
English
Weight
320 KB
Volume
138
Category
Article
ISSN
0026-9247

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Three new derivatives of vitamin B,, with a pyrrole head group attached to the corrin ring have been prepared. Ligdnd-exchange reactions and reduction provided reactive Co"' and Co" complexes. Their electrochemical properties and their potential for fixation at the surface of electrodes by electropo