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Synthesis and Structure of ThTe2I2

✍ Scribed by Frank Rocker; Wolfgang Tremel


Publisher
John Wiley and Sons
Year
2001
Tongue
German
Weight
99 KB
Volume
627
Category
Article
ISSN
0372-7874

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Figure 1. ORTEP drawing of 5 (50 % probability thermal ellipsoids for all non-hydrogen atoms, perchlorate anion is omitted for clarity). Selected bond lengths [Γ€] and angles [8]: S1-N1 1.526(2), S1-C1 1.695(2), S1-C2 1.780(3), S1-C3 1.802(3), S2-N2 1.531(2), S2-C1 1.691(2), S2-C4 1.788(3), S2-C5 1.8

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Reaction of K[(SePPh 2 ) 2 N] with [Te(tu) 4 ]Cl 2 (tu ‫ב‬ thiourea) in methanol gave [Te{(SePPh 2 ) 2 N} 2 ], (1), while reaction of K[(SPPh 2 ) 2 N] with 4-MeOPhTeCl 3 in methanol gave [4-MeOPhTe-{(SPPh 2 ) 2 N}] 2 , ( 2). The crystals of 1 are triclinic and contain centrosymmetric molecules. The