Figure 1. ORTEP drawing of 5 (50 % probability thermal ellipsoids for all non-hydrogen atoms, perchlorate anion is omitted for clarity). Selected bond lengths [Γ€] and angles [8]: S1-N1 1.526(2), S1-C1 1.695(2), S1-C2 1.780(3), S1-C3 1.802(3), S2-N2 1.531(2), S2-C1 1.691(2), S2-C4 1.788(3), S2-C5 1.8
Synthesis and Structure of (MeN)Ph2SCSPh2(NMe)
β Scribed by Takayoshi Fujii; Tomio Ikeda; Toshie Mikami; Tetsuya Suzuki; Toshiaki Yoshimura
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 106 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The neutral technetium(V) phosphoraneimine complex [TcNCl 2 (Ph 2 PNH) 2 ] is formed when (Bu 4 N)[TcOCl 4 ] reacts with Me 3 SiNPPh 3 in dichloromethane. Distances of 2.078(4) and 2.102(4) A Λhave been found between Tc and the neutral triphenylphosphoraneimine ligands. The Tc-N-P angles are 133.7(3
Diphenyl-o-silaborane (1) can be obtained by sublimation as colourless crystalline material in a yield of 23%. The disilaborane 1 was characterized by NMR spectroscopy, mass spectrometry and X-ray structure analysis. The neutral closo cluster 1 reacts with [Zr(NMe 2 ) 4 ] or [Ta(NMe 2 ) 5 ] to give
Reaction of cupferron [NH 4 L, L = PhN(O)NO -] with tin(IV), complex 2. The tin centers are heptacoordinated in a pentagonal bipyramidal geometry in the dimeric complex 3. diphenyltin(IV) and dimethyltin(IV) halides yields the cupferronato complexes SnL 4 (1), Ph 2 SnL 2 (2) and These complexes inco
H,-elimination from 3 must also occur [Eq. (e)]."ll Note that this equilibrium involves the same 16-electron species implicated in Equation (c). The product-forming hydrido-ethyl (A) and hydridoethyl ethylene (B) species (Scheme 1) "downstream" of reaction (d) have not been observed under a variety