Synthesis and structure of [Pt2(μ-H)(μ-CHCH2Ph)(diphos)2][BF4]
✍ Scribed by Prof. Dr. Giovanni Minghetti; Dr. Alberto Albinati; Dr. Anna Laura Bandini; Dr. Guido Banditelli
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 238 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
H,-elimination from 3 must also occur [Eq. (e)]."ll Note that this equilibrium involves the same 16-electron species implicated in Equation (c). The product-forming hydrido-ethyl (A) and hydridoethyl ethylene (B) species (Scheme 1) "downstream" of reaction (d) have not been observed under a variety
IPt,(dpPy),(Cc3-S),Ag3(Cc3-S)2Ptz(dPPY)41
The reactions of [Pt3R~6(CO),l(p-H)3(p3-H)] (1) with PMe3 and PPh3 have produced the salts [Pt(PR3)3H]-[Pt3R~6(CO)2,(p3-H)(p-H)2]r 5a and 5d, R = Me and Ph in the yields 9% and 22%, respectively. By contrast the reaction of 1 with PPh, in the presence of Me3N0 has yielded the phosphane-substituted d