Synthesis and structure of the ternary and quaternary strontium nitride halides, Sr2N(X, X′) (X, X′=Cl, Br, I)
✍ Scribed by Amy Bowman; Ronald I. Smith; Duncan H. Gregory
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 548 KB
- Volume
- 179
- Category
- Article
- ISSN
- 0022-4596
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The quaternary systems Ca-N-Cl-Br and Ca-N-Br-I have been investigated resulting in the synthesis of a number of new layered nitride mixed halides. The evolution of structure with composition has been investigated by powder X-ray and powder neutron diffraction techniques. A continuous solid solution
The first layered cobalt (II) oxide halides, Sr 2 CoO 2 Cl 2 and Sr 2 CoO 2 Br 2 , have been synthesized and their structures determined from Rietveld refinement of powder X-ray data. The materials are structural analogues of the K 2 NiF 4 cuprate phase Sr 2 CuO 2 Cl 2 , crystallizing in space group