Synthesis and structure of the first example of a four-electron donor, side-on bridging thiocarbonyl ligand
β Scribed by Doyle, Ruth Ann; Daniels, Lee M.; Angelici, Robert J.; Stone, F. Gordon A.
- Book ID
- 126226776
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 434 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0002-7863
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Reaction of Me 3 SiNPPh 2 Fc (Fc = ferrocenyl) with niobium pentachloride affords [NbCl 3 (NPPh 2 Fc) 2 ], whose redox-functionalised phosphaneiminato ligands exhibit remarkably different bend angles at nitrogen according to a crystal structure analysis.
polarization transfer from TP-Q, whereas after longer times spectra in pure emission develop owing to the differing recombination rates from the triplet sublevels (cf. Figs. 2 and3). A more exact analysis of the amplitude ratios of the high-field and low-field x',y' signals of 1 and 2 reveals a stro