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Synthesis and structure of the dimer Ir2Cl2I2(CO)2(μ-dppm )2]

✍ Scribed by Alessandra Crispini; Mauro Ghedini; Francesco Neve


Book ID
108327975
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
230 KB
Volume
209
Category
Article
ISSN
0020-1693

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✍ D.R. Striplin; J.A. Brozik; G.A. Crosby 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 452 KB

Excitation spectra, photoemission spectra, and phosphorescence decay times were measured on the title compound. Results are consistent with an Ir( I) -Au (I) orbital promotion leading to a lowest 'A, state and a corresponding low-lying 'A, term that splits into (B,, B,)Bnd A2 states by spin-orbit co